Modern Arylation Methods

ARYLATION REACTIONS: A HISTORICAL PERSPECTIVEStructure and Bonding of BenzeneSyntheses of Substituted (Hetero)Arenes, and the Contents of this BookMETAL-CATALYZED COUPLING REACTIONS WITH ARYL CHLORIDES, TOSYLATES AND FLUORIDESIntroductionCoupling Reactions of Aryl ChloridesCoupling Reactions Aryl FluoridesCoupling Reactions of Aryl TosylatesPALLADIUM-CATALYZED ARYLATIONS OF AMINES AND ALPHA-C-H ACIDIC COMPOUNDSIntroductionPalladium-Catalyzed Arylations of AminesPalladium-Catalyzed Arylations of Alpha-C-H Acidic CompoundsCOPPER-CATALYZED ARYLATIONS OF AMINES AND ALCOHOLS WITH BORON-BASED ARYLATING REAGENTSIntroductionDiscovery and Development of a New O-H Bond Arylation Reaction: From Stoichiometric to Catalytic in CopperMechanistic ConsiderationsMiscellaneous ApplicationsDevelopment of a New N-H Bond Arylation ReactionDevelopment of a New N-H Bond Arylation Reaction: Catalytic in CopperMETAL-CATALYZED ARYLATIONS OF NONACTIVATED ALKYL (PSEUDO)HALIDES VIA CROSS-COUPLING REACTIONSIntroductionPalladium-Catalyzed Arylations of Alkyl (Pseudo)HalidesNickel-Catalyzed Arylations of Alkyl (Pseudo)HalidesIron-Catalyzed Arylations of Alkyl (Pseudo)HalidesCopper- and Cobalt-Catalyzed Arylations of Alkyl (Pseudo)HalidesARYLATION REACTIONS OF ALKYNES: THE SONOGASHIRA REACTIONIntroductionPalladium-Catalyzed Reactions: Ligands and Reaction ProtocolsAlternative Metal CatalystsMechanism of the Sonogashira ReactionPALLADIUM-CATALYZED ARYLATION REACTIONS OF ALKENES (MIZOROKI-HECK REACTION AND RELATED PROCESSES)IntroductionMizoroki-Heck ArylationsReductive Mizoroki-Heck-Type ArylationsOxidative Mizoroki-Heck-Type ArylationsMODERN ARYLATIONS OF CARBONYL COMPOUNDSIntroductionEnantioselective Arylation of AldehydesEnantioselective Arylation of KetonesEnantioselective Arylation of IminesConjugate Asymmetric ArylationTandem ProcessesEnantioselective Friedel-Crafts ArylationMETAL-CATALYZED DIRECT ARYLATIONS (EXCLUDING PALLADIUM)IntroductionRhodium-Catalyzed Direct ArylationsRuthenium-Catalyzed

Lutz Ackermann obtained his Ph.D. in the group of Alois Fürstner at the Max-Plank-Institut für Kohlenforschung in Mülheim, Germany. After a postdoctoral stay with Robert G. Bergman at the University of California at Berkeley, USA, he initiated his independent career at the Ludwig-Maximilians-University Munich. His recent awards include an Emmy Noether `Junior Research GroupŽ from the DFG, a DuPont Center for Collaborative Research & Education Grant, a Thieme journal-award, and an ORCHEM-Price from the GDCh.